What is isomerism?

Isomers are compounds that have the same molecular formula, but different arrangements of atoms. There are two main types of isomerism: structural isomerism and stereoisomerism.

Structural isomerism

  • In structural isomers, the chemical formula remains the same but the structural formula changes. 
  • Position isomerism occurs when the location of the functional group varies in each isomer. 
  • Functional group isomerism occurs when there are different functional groups present. 
  • Chain isomerism occurs when isomers differ in the structure of their carbon 'skeleton'.
Mobirise Website Builder

Stereoisomerism

  • Stereoisomers are compounds whose molecules have the same atoms bonded to each other, but with different arrangements of the atoms in space. 
  • Geometrical (cis/trans) isomerism occurs due to the restricted rotation about a C=C double bond. In cis isomers, the substituents are on the same side of the double bond, while in trans isomers, they are on opposite sides. 
  • Optical isomerism occurs when a molecule contains a carbon atom bonded to four different atoms or groups of atoms. This carbon atom is called a chiral centre. The two  isomers, called enantiomers, are mirror images of each other and cannot be superimposed. 
Mobirise Website Builder